Hyperbranched polyamidoamine-grafted silica was prepared according to dendrimer synthesis methodology. The modified silica was dispersed uniformly in epoxy resin, and the curing of epoxy resin proceeded successfully by heating in the presence of the modified silica; the gel fraction of the epoxy resin cured by the hyperbranched polyamidoamine-grafted silica (grafting = 80.2%) reached 77% at 170 degreesC after 48 h. The gel fraction increased with increasing terminal amino group content of the hyperbranched polyamidoamine-grafted silica. In addition, the curing ability of the silica increased by complexation of the terminal amino groups of the grafted polyamidoamine with boron trifluoride. The modulus of elasticity of the curing materials obtained using the modified silica as a curing agent was lower than that using conventional a curing agent such as ethylenediamine in the presence of untreated silica. On the other hand, the heat resistance of the curing product using the modified silica was superior to that using ethylenediamine, but no difference in glass-transition temperature was observed. It is expected that hyperbranched polyamidoamine grafted-silica is incorporated uniformly with chemical bonds in the matrix of the epoxy resin.