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Journal of Polymer Science Part A: Polymer Chemistry, Vol.39, No.7, 1136-1148, 2001
Co- and terpolymerization of ethylene, propylene, and higher alpha-olefins with high propylene contents using metallocene catalysts
The copolymerization of propylene/ethylene and terpolymerization of propylene/ethylene/alpha -olefins using long-chain alpha -olefins such as 1-octene and 1-decene have been carried out using EtInd(2)ZrCl(2)//methylaluminoxane. High concentrations of propylene and low concentrations of alpha -olefins (near 2 mol % of the total olefin concentration in the liquid phase) were used. The effect of the ethylene concentration in copolymerizations of propylene/alpha -olefins was studied at medium ethylene contents (12 and 40 mol % in the gas phase). The polymers were molecularly characterized by gel permeation chromatography-multiangle laser light scattering, wide-angle X-ray scattering, Fourier transform infrared spectroscopy, and DSC analyses. The shorter alpha -olefin studied (1-octene) produced the highest improvement of activity in terpolymerization at 12 mol % ethylene in the gas phase. About 2 mol % of 1-octene in the liquid phase increases the activity and decreases the molecular weight of terpolymers with respect to corresponding copolymers, whereas the mp is increased by almost 30 degreesC. The "termonomer effect" is less evident when higher amounts of ethylene are used. (C) 2001 John Wiley & Sons, Inc.
Keywords:propylene copolymerization;propylene terpolymerization;long-chain alpha-olefins copolymerization