Polypropylene (PP) blends, commercially known as "impact polypropylene copolymers" (IPC), are produced by a sequential gas phase polymerization process. The final product is a complex mixture of polypropylene (PP) and a range of ethylenepropylene copolymers (EPC) with different ethylene contents. In the present work, the composition of three different IPC was estimated by performing a step elution mode Analytical Temperature Rising Elution Fractionation (TREF) separation. The recovered fractions were analyzed by Differential Scanning Calorimetry (DSC), Size Exclusion Chromatography (SEC) and Fourier Transform Infrared Spectroscopy (FTIR). The morphology was examined by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). Amorphous EPC were isolated in an independent way in order to perform a more careful characterization. The distinct particle size and shape of the dispersed phase for different IPC was interpreted in terms of the molecular characteristics of the blend components and their compositions.