Catalysis Letters, Vol.68, No.1-2, 105-108, 2000
An investigation of the selective oxidation of NH3 to N-2 in gasified biomass in the presence of excess CO and H-2 using zeolite catalysts
The selective oxidation of NH3 to N-2 in simulated biogas containing a large excess of CO and H-2 has been examined using zeolite catalysts. Of the materials examined zeolite Beta gave the highest N-2 yield (85% at 475-575 degrees C), while ZSM5 produced 75% at 575 degrees C, but HY was both less active and selective. In all cases N-2 is formed via an internal selective catalytic reduction between NOx (derived from the oxidation of NH3) and NH3 adsorbed on Bronsted sites of the zeolite.