The carbon and nitrogen K-shell excitation spectra of gaseous pyridine and pyridazine were recorded using the electron-energy loss spectroscopy under electric-dipole conditions (2 keV, small angle) with a resolution of 0.2 eV. Ab initio Configuration interaction calculations in the frame of the equivalent core model were performed in order to help in the assignment of the spectral features. The spectra are dominated by the transitions to the 1 pi* and sigma* type orbitals. The C1s spectra of both molecules are close to that of benzene: The intensity of Rydberg transitions are enhanced by an important valence sigma(C-H)* character; the 1s --> 3 pi* transition is mixed with double excitations and give rise to several states, some of them lying above the ionization thresholds. Finally, the N1s spectra of both molecules are similar to the s-triazine one.