Rigid-body diffusion Monte Carlo simulations of the ground state and ten low-lying intermolecular excited vibrational states for the cage form of (H2O)(6) are reported. The excited states are found by a nodal optimization procedure in which the fundamental excited-state nodes are constructed from the harmonic normal coordinates. The anharmonic effects in the excited states are found to be large. One of the states with relatively large transition intensity involves primarily flipping motions of the free OH bonds on the doubly bound monomers, and is assigned to the vibration-rotation-tunnelling band observed experimentally by Liu [Nature 301, 501-503 (1996)].