The influence of hydrogen-bond formation on the scalar spin-spin coupling constants and NMR shielding constants in CH2O-H2O, C2H2-H2O, CH3OH-H2O, and (HCOOH)(2) complexes has been calculated using correlated MO (MCSCF and MP2) methods. The hydrogen-bond transmitted spin-spin coupling constants are also reported. The iso- and anisotropic H-1 shielding constants are found to be the most general parameters of the hydrogen bond. The changes in (1)J(XH) coupling in the proton donor also correlate with the XH ... Y hydrogen bond strength. A similar correlation is found in the intermolecular (1h)J(HY) and (2h)J(XY) couplings. These couplings are substantial and dominated by the Fermi-contact term in contrast to the longer-range hydrogen-bond transmitted couplings where the noncontact terms prevail.