Electron impact total ionization cross-sections of small silicon hydrides, SiHn(n=1-4), and fluorides, SiFn(n=1-3), have been calculated by the application of a recently developed theoretical model. The binary-encounter-Bethe (BEB) model has a simple structure and requires information from calculations on the parent ground-state molecule only (binding energies, orbital kinetic energies, and occupation numbers). Previous applications of the BEB theory to the silicon hydrides and fluorides have employed a combination of experimental and Koopman's theorem binding energies. In the current work binding energies have been calculated using the explicitly correlated multiconfigurational spin tensor electron propagator (MCSTEP) method which gives highly accurate ionization potentials for closed- and open-shell systems. Calculations have been performed using cc-pVDZ and cc-pVTZ basis sets with multiconfigurational self-consistent field (MCSCF) reference wave functions. Comparisons are made between our MCSCF/MCSTEP and previous Hartree-Fock (HF)/Koopman's theorem results and available experimental data. The use of improved theoretical data does not have a significant effect on the resultant cross-sections; however, our new technique is a viable method for calculating electron impact ionization cross-sections for systems where Koopman's theorem is known to be unreliable or no experimental data is available.