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Journal of Chemical Physics, Vol.114, No.16, 6969-6972, 2001
The equilibrium theory for Lennard-Jones dimer fluids
We develop a new analytic theory for the thermodynamics of a fluid of dimers consisting of Lennard-Jones or Lennard-Jones-type atoms. The theory uses a hard-dimer reference system and an extension of the Weeks-Chandler-Andersen approach from a monatomic to a polyatomic fluid.