Journal of Chemical Physics, Vol.114, No.24, 10577-10578, 2001
Relationship between kinetics and thermodynamics of supercooled liquids
We show that a single, reasonable assumption about the probability of rearrangements in a supercooled liquid necessarily implies a direct connection between kinetic and thermodynamic observables in these media. The prediction is tested against available experimental data for supercooled liquids spanning the range of observed kinetics.