화학공학소재연구정보센터
Journal of the Electrochemical Society, Vol.147, No.2, 751-755, 2000
Analysis of selectively grown epitaxial Si1-xGex by spectroscopic ellipsometry and comparison with other established techniques
The increased interest in epitaxial Si1-xGex/Si heterostructures for device applications requires very good control of layer thickness and composition. Unfortunately, most of the well-developed characterization methods, such as Rutherford backscattering spectroscopy (RBS), secondary ion mass spectroscopy, and photoluminescence measurements are unsuitable as production measurement tools. On the other hand, spectroscopic ellipsometry (SE) allows a fast, in-line, and nondestructive analysis, including wafer mapping capabilities. This paper demonstrates the suitability of SE for the determination of both Ge content and layer thickness of epitaxial Si1-xGex for Ge contents between 1 and 35%. By describing the optical dispersion by means of the harmonic oscillator model, we obtained a clear correlation between the Ge content and E-n(1), the resonant energy of the first oscillator, and n(max), the peak value of the real part of the refractive index. The small spot (30 x 30 mu m) size allows one to characterize Si1-xGex layers selectively grown in an isolation structure. The small window size prevents RES measurements. SE allowed the fine tuning of a selective epitaxial growth process with regard to growth rate, Ge incorporation, and wafer uniformity.