화학공학소재연구정보센터
Journal of Materials Science, Vol.34, No.18, 4385-4392, 1999
Dense Ti3SiC2 prepared by reactive HIP
The dense polycrystalline Ti3SiC2 has been synthesized by reactive HIPing of Ti, SiC and C powders. The bulk material with the highest Ti3SiC2 content about 97 vol % was obtained when treated at 1500 degrees C, 40 MPa for 30 min. The density was 99% of the theoretical value. The Ti3SiC2 grains had the columnar and plate-like shapes. The grains were well boned to form a network structure. Many stacking faults were observed along the (001) plane of Ti3SiC2. The Vickers hardness, Young's modulus, flexural strength and fracture toughness were 4 GPa, 283 GPa, 410 MPa and 11.2 MPa m(1/2), respectively. The Ti3SiC2 was stable up to 1100 degrees C in air. The electrical resistivity was 2.7 x 10(-7) Omega . m at room temperature. The resistivity increased linearly with the increasing temperature. It may be attributed to a second order phase transition. The Seebeck coefficient was from 4 to 20 mu V/K in the temperature range 300-1200 K. It seems that Ti3SiC2 is semi-metallic with hole carriers from this small positive value.