화학공학소재연구정보센터
Journal of Materials Science, Vol.34, No.18, 4597-4599, 1999
Infrared study of relevance of Nd2CuO4 structure to superconductivity of La-Sr-Cu-O system
A comparative study of the infrared spectra of Nd2Cu1-xAgxO4 and La1.8Sr0.2Cu1-xAgxO4 is reported. It is shown that the appearance of an absorption peak at similar to 680 cm(-1) is due to local distortions around the Ag impurities, and the appearance of this peak need not imply a structural transformation from Nd2CuO4 type of K2NiF4 type. It is shown that Nd2CuO4 structure is not important for the superconductivity of La-Sr-Cu-O system.