Journal of Applied Polymer Science, Vol.67, No.1, 87-92, 1998
Preparation and mechanical properties of polypropylene-clay hybrids using a maleic anhydride-modified polypropylene oligomer
Polypropylene-clay hybrids (PPCH) were prepared using a maleic anhydride-modified PP oligomer (PP-MA) as a compatibilizer. PP was melt-blended with organophilic clay which was intercalated with PP-MA. In these PPCHs, the particles of silicate layers were dispersed at the nanometer level. The particles became smaller and were dispersed more uniformly, as the ratio of PP-MA to the clay was increased. The dynamic storage moduli of the PPCHs were higher than that of PP up to 130℃. For example, the modulus of the PPCH with 5 wt % clay and 22 wt % PP-MA was 1.8 times higher compared to that of PP at 80℃. As the dispersibility of the clays was improved, the reinforcement effect of the clays increased.