Journal of Applied Polymer Science, Vol.78, No.11, 1971-1976, 2000
Lower critical solution temperature of linear PNIPA obtained from a Yukawa potential of polymer chains
The lower critical solution temperature (LCST) behavior of a linear poly(N-isopropylacrylamide) (PNIPA) in water is thought to result from the polymer-polymer attractive interaction. This polymer-polymer attraction is modeled by a temperature-dependent Yukawa attractive potential, with Yukawa parameters determined by fitting the theoretical phase diagram for a pure Yukawa fluid to the experimental lower consolute boundary for a PNIPA-water solution. The predicted coexistence curve for the PNIPA-water mixtures in the temperature-polymer volume fraction plane is reasonably close to the experimental cloud point data for the PNIPA-water system.
Keywords:poly(N-isopropylacrylamide) (PNIPA);lower critical solution temperature (LCST);Yukawa potential;polymer-polymer interaction;coexistence curve