Negatively charged benzene clusters, (benzene)(n)(-), were produced by injecting low- and high-energy electrons into an intense supersonic jet expansion. Threshold size of n=53 was observed by slow-electron attachment, while the smaller (benzene)(n)(-) with 2 less than or equal ton less than or equal to 52 were also observed through the fragmentation of larger (benzene)(n)(-) by high-energy electron attachment. Photoelectron spectroscopy for (benzene)(n)(-) with n=53-124 has revealed a bulklike electron solvated state in (benzene)(n greater than or equal to 53)(-) through the vertical detachment energies (VDEs) versus n(-1/3) relationship.