Journal of Applied Polymer Science, Vol.82, No.11, 2784-2789, 2001
Flow behavior of polyacrylamide solution. III. Mathematical treatment
The flow behavior of polyacrylamide solutions was systematically determined over a wide range of temperatures (20-50 degreesC) and concentrations (20-50 ppm) by using a coaxial cylinder viscometer. The results indicated that the rheological behavior of low-concentration polyacrylamide solution behaves similar to non-Newtonian fluids at all these concentrations. The effect of temperature on the consistency coefficient and flow behavior index of polyacrylamide solution of the different concentrations followed an Arrhenius-type relationship. Moreover, the effect of concentration on consistency coefficient and flow behavior index followed an exponential-law relationship at the temperatures used. The rheological constants for the Arrhenius and exponential-law models were determined. The combined effect of temperature and concentration on the coefficient of dynamic shear stress can be represented by a single equation: shear stress = 2.446 X 10(-7) exp(0.0639C + 3613/RT)(shear rate)(2.337 exp(-0.00707C-245/RT)).
Keywords:polyacrylamide;flow behavior