화학공학소재연구정보센터
HWAHAK KONGHAK, Vol.27, No.1, 33-41, February, 1989
중금속 황화물 침전의 기-액계면 흡착분리에 관한 연구
Separation of Heavy Metal Sulfide by Precipitate Foam Adsorption
초록
중금속 황화물의 기-액계면 흡착분리 특성을 고찰하고 최적조건을 구하기 위해 단일 및 혼합계에 대하여 계면 흡착분리 실험을 하였다. 미립자의 기-액계면 흡착을 상승기포와 입자간의 충돌에 의한 흡착으로 가정하면 미립자의 잔류농도와 분리시간간의 관계는 다음과 같은 식으로 표시될 수 있었다.
C = Co exp [ - 3/4 f ( Gh/Va ) t ]
포집효율에 미치는 공기유속효과, 관 높이, EHDA-Br 농도의 영향을 검토하였으며, 포집효율은 응집을 위한 EHDA-Br의 최적농도에서 최대였으며 중금속 1mole당 최적 EHDA-Br의 몰수는 금속종류에 따라 0.06-0.13mole이다.
In order to investigate the characteristics and the optimum condition of the gas-liquid interface adsorp-tive separation of metal sulfides, the coagulation-dispersion and the adsorptive separation of the single and mixed systems were experimentally carried out, and the adsorptive separation model was considered. Theoretically, the separation rate of fine particles by gas-liquid interface adsorption was derived under the assump-tion of adsorption by collision between rising bubbles and particles. The relation between the residual concentration of fine particles and the bubbling time was obtained as follows and this equation proved successful with the experimental results.
C=Co exp[-(3/4)fㆍ(Gh/Va)ㆍt]
The effects of air flow rate, column height and ethylhexadecyldimethylammonium bromide(EHD-Br) concen-tration on the collection effciency have experimentally been investigated. The collection efficiency was maximum at the optimum concentration of EHDA-Br for the coagulation, i.e., 0.06-0.13moles of EHD-Br per unit mole of metal sulfides.