Donor-acceptor complexes MX3-D (M = Al, Ga, In; X = F, Cl, Br, I; D = YH3, PX3, X-; Y = N, P, As) and their components have been studied using self-consistent field and hybrid Hartree-Fock/density functional (B3LYP) methods with effective core potentials. The theoretical dissociation energies of the MX3-D complexes decrease in the orders F > Cl > Br > I, Al > Ga < In, and N much greater than P greater than or equal to As for all investigated complexes, The calculated (B3LYP/LANL2DZP) dissociation energies for ammonia adducts are on average 7 kT mol(-1) higher than those from experiment. There is no correlation between the dissociation energy and the degree of charge transfer. Complexes of ammonia and metal fluorides have mostly ionic metal-donor bonds, while the other donor-acceptor adducts are mostly covalently bonded. In addition, a significant charge redistribution between the terminal atoms leads to further electrostatic stabilization of ammonia adducts. Coulomb interactions destabilize MX3-PX3 complexes, and despite some experimental indications, the existence of these particular complexes in the gasphase is improbable. Distortion of MX3 from planarity under complex formation leads to decreasing X-M-X angles. These decreasing angles correlate well with increasing M-X bond lengths. For all investigated MX3-X- systems a strong correlation of the MX3-X- dissociation energy with the M-X bond length increase is found. Correlations between the pyramidal angle X-M-Y and the length of the adjacent M-Y bond have been found for each donor atom Y. All observed trends in structural and thermodynamic properties are qualitatively explained on the basis of a simple electrostatic model.