Canadian Journal of Chemical Engineering, Vol.73, No.3, 357-366, 1995
Ultrapyrolysis of Automobile Shredder Residue
A fast pyrolysis (Ultrapyrolysis) process was employed to convert automobile shredder residue (ASR) into chemical products. Experiments were conducted at atmospheric pressure and temperatures between 700 and 850 degrees C with residence times between 0.3 and 1.4 seconds. Pyrolysis products included 59 to 68 mass% solid residue, 13 to 23 mass% pyrolysis gas (dry) and 4 to 12 mass% pyrolytic water from a feed containing 39 mass% organic matter and 2 mass% moisture. No measurable amounts of liquid pyrolysis oil were produced. The five most abundant pyrolysis gases, in vol%, were CO (18-29), CO2 (20-23), CH4 (17-22), C2H4 (20-22) and C3H6 (1-11), accounting for more than 90% of the total volume. The use of a higher organic content ASR feed (58 mass %) resulted in less solid residue and more pyrolysis gas. However, no significant changes were noted in the composition of the pyrolysis gas.
Keywords:CONTINUOUS FLASH PYROLYSIS;VACUUM-PYROLYSIS;MOLECULAR CHARACTERIZATION;LIQUID PRODUCTS;BIOMASS;WOOD;REACTOR;WASTE;OILS