화학공학소재연구정보센터
Journal of Physical Chemistry A, Vol.104, No.37, 8489-8495, 2000
Solubility of HBr in H2SO4/H2O and HNO3/H2SO4/H2O solutions
The solubility of HBr in H2SO4/H2O and HNO3/H2SO4/H2O solutions was determined by measuring the HBr vapor pressure over stirred bulk solutions using tunable diode laser spectrometry. The experimental results for the solubility of HBr in sulfuric acid solutions show good agreement with experimental literature data. However, there is a factor 2-6 discrepancy between experimental and model values. The solubility of HBr in sulfuric acid was parameterized as a function of the H2SO4 concentration and temperature in the range 53-75 wt % H2SO4 and 195-250 K, respectively. The solubility of HBr in ternary HNO3/H2SO4/H2O solutions was determined for the first time. An increase in the solubility was observed on exchanging H2SO4 by HNO3 at constant water weight fraction. This observation is in qualitative agreement with model calculations, however, the observed solubility change was much larger than predicted by the model calculations. The solubility of HBr in ternary solutions was parameterized as a function of both the concentration of HNO3/H2SO4 and the temperature. The relations derived can be used for atmospheric modeling of the influence of heterogeneous HBr reactions on atmospheric ozone destruction.