Inorganic Chemistry, Vol.39, No.18, 4179-4181, 2000
The vanadium(V) borophosphate (NH4)(5)[V3BP3O19]center dot H2O
The vanadium borophosphate (NH4)(5)[V3BP3O19]. H2O has been synthesized at room temperature under oxidizing conditions. The cluster anion [V3BP3O19](5-) contains three edge-shared distorted VO6 octahedra and is the first example of a V(V) borophosphate.