Inorganic Chemistry, Vol.40, No.11, 2474-2475, 2001
Dimeric gallium oxide and sulfide species stabilized by a sterically encumbered beta-diketiminate ligand
Reaction of {HC(MeCDippN)(2)}Ga: with N2O or S-8 produces the compounds [{HC(MeCDipDN)(2)}GaE](2) (E = O or S), which are unique examples of gallium oxide and sulfide dimers stabilized by a chelating ligand. [GRAPHICS]