Inorganic Chemistry, Vol.40, No.17, 4494-4499, 2001
Electronic structure of low-spin ferric chlorins: Characterization of bis(dimethylphenylphosphine)(meso-tetraphenylchlorinato)iron(III) triflate
The title compound has been prepared by the reaction of dimethylphenylphosphine and (mesotetraphenylchlorinato) iron(DI) triflate. Its structural characteriztion demonstrates that the low-spin iron (III) atom is centerd in the heme plane with a radial expansion of the chlorinato core. [GRAPHICS]