중유회분으로부터 Vanadium 및 Nickel 성분의 회수에 관한 연구

서원경; 김재용; 김원배; 유영홍; 이철태

HWAHAK KONGHAK, Vol.28, No.6, 659-668, December, 1990

Export Citation

중유회분으로부터 Vanadium 및 Nickel 성분의 회수에 관한 연구

Extraction of Vanadium and Nickel Components from Petroleum Oil Ash

서원경, 김재용, 김원배, 유영홍, 이철태

초록

본 연구는 중유회분으로부터 유효성분 vanadium 및 nickel을 추출할 수 있는 새로운 방법을 찾기 위해 시도되었다. 이 공정은 2단계 공정으로 진행되었으며 먼저 water leaching에 의해 vanadium 및 nickel성분을 회수하였으며 다음 공정으로 （NH₄）₂SO₄에 의한 황산화 반응을 통하여 계속적으로 vanadium과 nickel 성분을 회수하였다. 황산화 반응에 대한 적정조건은 반응온도 350℃, 반응시간 10분, 황산암모늄의 petroleum oil ash에 대한 무게비 3.0이었다. 이상의 과정을 통하여 vanadium은 97.90%, nickel은 91.31%가 각각 회수되었다.

This study was carried out to find a new process for the extraction of vanadium and nickel component from the petroleum oil ash. This process was proceeded in two steps as follows; the first step was recovery of vanadium and nickel components directly through water leaching treatment of the petroleum oil ash and the second step was the sulfation of the residue from the water leaching with (NH₄)₂SO₄. The proper conditions of the sulfation were reaction temperature 350℃, reaction time 10min and (NH₄)₂SO₄ weight ratio to the petroleum oil ash 3.0. Under above mentioned conditions, 97.90% vanadium and 91.31% nickel components were extracted from the petroleum oil ash, respectively.

[References]

Kirk and Othmer: "Encyclopedia of Chemical Engineering," 3rd ed., John Wiley & Sons (1984)
자원개발연구소: "자원총람", 1st ed., 자원개발연구소, 서울 (1980)
Habashi F, "Principles of Extractive Metallurgy," vol. 2, Gordon & Breach, New York (1970)
이승이, "비철금속 제련공학," 문운당, 서울 (1976)
Islam F, Biswas RK, J. Inorg. Nucl. Chem., 42, 415 (1980)
Choi CS, Oh KJ, Lee WH, Kang WK, HWAHAK KONGHAK, 18(3), 153 (1980)
Gomesz CO, Spink DR, Rompel GL, Metallurgical Transaction B, 12, 341 (1982)
최한석, 홍윤명, "무기공업화학," 동명사, 서울 (1983)
Halstead WD, J. Appl. Chem., 20, 129 (1970)
Kiyoura R, Urano K, Ind. Eng. Chem. Process Des. Dev., 9, 529 (1973)
Miyamoto A, Yamazaki Y, Murakami Y, Jpn. J. Chem., 619 (1977)
Snell FD, "Encyclopedia of Industrial Chemical Analysis," John Wiley & Sons, New York (1979)
Lee CT, Namgoong Y, Yoo YH, HWAHAK KONGHAK, 26(3), 295 (1988)

[1] Kirk and Othmer: "Encyclopedia of Chemical Engineering," 3rd ed., John Wiley & Sons (1984)

[2] 자원개발연구소: "자원총람", 1st ed., 자원개발연구소, 서울 (1980)

[3] Habashi F, "Principles of Extractive Metallurgy," vol. 2, Gordon & Breach, New York (1970)

[4] 이승이, "비철금속 제련공학," 문운당, 서울 (1976)

[5] Islam F, Biswas RK, J. Inorg. Nucl. Chem., 42, 415 (1980)

[6] Choi CS, Oh KJ, Lee WH, Kang WK, HWAHAK KONGHAK, 18(3), 153 (1980)

[7] Gomesz CO, Spink DR, Rompel GL, Metallurgical Transaction B, 12, 341 (1982)

[8] 최한석, 홍윤명, "무기공업화학," 동명사, 서울 (1983)

[9] Halstead WD, J. Appl. Chem., 20, 129 (1970)

[10] Kiyoura R, Urano K, Ind. Eng. Chem. Process Des. Dev., 9, 529 (1973)

[11] Miyamoto A, Yamazaki Y, Murakami Y, Jpn. J. Chem., 619 (1977)

[12] Snell FD, "Encyclopedia of Industrial Chemical Analysis," John Wiley & Sons, New York (1979)

[13] Lee CT, Namgoong Y, Yoo YH, HWAHAK KONGHAK, 26(3), 295 (1988)