화학공학소재연구정보센터
Journal of Materials Science, Vol.36, No.20, 4961-4967, 2001
Mechanical and elastic properties of transparent nanocrystalline TeO2-based glass-ceramics
Mechanical and elastic properties of transparent TeO2-based glass-ceramics (15K(2)O . 15Nb(2)O(5) . 70TeO(2)) consisting of nanocrystalline particles (each particle size: 40-50 nm) and showing optical second harmonic generation were evaluated by means of usual Vickers indentation and nanoindentation tests. The precursor glass has Vickers hardness H-v of 2.9 GPa, Young's modulus E of 54.7 GPa, the fracture toughness K-c of 0.25 MPam(1/2) and Poisson's ratio of 0.24. The transparent nanocrystalline glass-ceramic heat-treated at 420 degreesC for 1 h has H-v = 3.8 GPa, E = 75.9 GPa and K-c = 0.34 MPam(1/2), and the opaque glass-ceramic heat-treated at 475 degreesC for 1 h has H-v = 4.5 GPa, E = 82.9 GPa and K-c = 0.68 MPaM1/2, demonstrating that poor mechanical and elastic properties of the precursor TeO2-based glass are improved through sufficient crystallization. The fracture surface energy, brittleness and elastic recoveries (about 44%) after unloading (the maximum load: 30 mN) of transparent nanocrystalline glass-ceramics are almost the same as those of the precursor glass, implying that the interaction among nanocrystalline particles is not so strong.