Journal of Vacuum Science & Technology B, Vol.18, No.6, 3414-3418, 2000
Nanoscale patterning of self-assembled monolayers with electrons
We show the fabrication of gold nanostructures using self-assembled monolayers of aliphatic and aromatic thiols as positive and negative electron beam resists. We applied a simple and versatile proximity printing technique using focused ion beam structured stencil masks and low energy (300 eV) electrons. We also used conventional e-beam lithography with a beam energy of 2.5 keV and doses from 3500 to 80 000 muC/cm(2). Gold patterns were generated by wet etching in KCN/KOH and characterized by atomic force microscopy and scanning electron microscopy. The width of the finest lines is similar to 20 nm; their edge definition is limited by the isotropic etching process in the polycrystalline gold.