Journal of Colloid and Interface Science, Vol.212, No.1, 130-134, 1999
Approximate expression for the double-layer interaction energy between two parallel plates with constant surface charge density
An approximate expression for the potential energy of the double-layer interaction between two parallel similar plates with constant surface charge density is derived via a novel linearization method, in which the Poisson-Boltzmann is linearized with respect to the deviation of the electric potential from the surface potential (which is a function of the interplate separation h). This approximation works quite well for small plate separations h for all values of the surface charge density (or the unperturbed surface potential) and gives a correct limiting form of the interaction energy (or the interaction force) as h --> 0.