Excess molar volumes V-E have been investigated from density p measurements using vibrating-tube digital densimeter DMA 60/602 for binary mixtures of methanol, 1-propanol, 2-propanol and 1-hexanol with ethyl acetate in the temperature range 298.15-323.15 K. Thermal expansion coefficients a and their excess values alpha (E) were evaluated. The results were analyzed and discussed in terms of dependence of V-E on chain length of alkanol and position of hydroxyl group and effect of temperature.