Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.342, 237-240, 2000
Synthesis and characterization of new pi-conjugated polymer complexes with transition metal fragments
Poly(2,2'-bipyridine-5,5'-diyl) (PBpy) (1) and a polymer of 2,2'-bipyrimidine (PBpym) (2) afford polymer complexes (3) and (4) coordinated with [Ru(bpy)(2)](2+) fragments, respectively. The UV-vis spectrum of (4) in cone. H2SO4 is considerably different from 2 in cone. H2SO4 The poly(6,6-dimethylbipyridine-5,5'-diyl)(P6MeBpy) (5) reacts with a ruthenium complex, [RuClCp*](4), (Cp* = pentamethylcyclopentadienyl) to give a new ruthenium complex (6).
Keywords:pi-conjugated polymer;pi-conjugated polymer complex;ruthenium complex;poly(2,2 '-bipyridine-5,5 '-diyl);poly(2,2 '-bipyrimidine-5,5 '-diyl)