Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.343, 371-376, 2000
Second-order nonlinear optical properties of the hybrid-film of a clay and a chiral metal complex
Second-harmonic generation (SHG) properties of the hybrid-films of a clay and [Delta-Ru (4,7-diphenyl-1,10-phenanthroline)(3)](ClO4)(2) (Delta-Ru(dpp)(3)), which was found to be stable enough over a very long time, were studied. The ratio of the SHG signal intensity between Z- and Y-Type films of Delta-Ru(dpp)(3) has been compared. Furthermore. the SHG coefficient d(33) at 1.06 mu m is determined as 30 pm/V for the Y-Type hybrid-film of Delta-Ru(dpp)(3).