Novel CT complexes derived from 4-alkylamino-TEMPO radical and 2,4,6,8-tetracyanoazulene have been prepared. Curie-Weiss behavior has been observed in the magnetic susceptibility of each complex with antiferromagnetic spin-spin interactions in the low temperature region on one hand and rather high conductivity has been found in the electrical conductivity of each complex with semiconducting behavior on the other hand.