A system of nanometer sized Pd crystals in fullerenes was grown by thermal deposition of fullerenes C-60/C-70 mixture (C-60:C(70)ratio was 8:2) and Pd organic compound from two separated sources. Films were deposited on the various substrate (fuse silica, copper band, molybdenum band and semiconducting Si). Obtained films were studied by TEM, ED, SEM and ESCA methods showing that films are composed of 2.5nm Pd clusters situated in fullerenes matrix. The bias voltage applied along the film caused the creation of electrical conductivity paths. After the formation of electrical conductivity path electron emission was observed for film (on fused silica) placed in diode system. These paths were formed of the nanometer sized Pd crystals. As a result of such structural changes we observed enhanced field emission from the film.