Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.365, 1745-1758, 2001
The lyotropic smectic phase on the Flory lattice
The Flory lattice approach for rod-like molecules is extended to encompass the position-restricted (smectic-A) phase. The phase equilibria conditions are obtained from equity of relevant chemical potentials, together with minimization conditions of the Gibb potential with respect to the system orientational (Flory disorder index, y) and positional (translational disorder index, xi. in the smectic phase) order.