화학공학소재연구정보센터
Catalysis Today, Vol.24, No.1-2, 189-194, 1995
Autoxidation of Methoxytoluene in Acetic-Acid - Electrochemical Assistance of the Catalytic Effect of Cobalt
Liquid phase autoxidation of p-methoxytoluene to p-anisaldehyde in water-acetic acid medium (10-90% vol.) using cobalt acetate as a catalyst has been investigated under or not electrolysis between two graphite electrodes. The rate of formation of anisaldehyde is strongly increased under electrolysis condition : the maximum anisaldehyde yield occurs at t=70 min whereas this maximum is reached only after t=5 h 30 min without electrolysis.