Blends of two different thermotropic liquid crystalline polymers, poly(p-hydroxy benzoic acid-co-2, 6-hydroxy naphthoic acid), VA, and poly(p-hydroxybenzoic acidco-terephthalic acid-co-aminophenol), VB, were obtained by direct injection molding throughout the full composition range. The blends were almost fully immiscible apart from a low degree of reaction. This, as well as the nature of the blends, probably influenced their mechanical properties. Enhanced properties were obtained both in the modulus of elasticity and in the tensile strength, at all the compositions studied, with absolute maxima at VB contents between 50% and 75%. These synergisms were mainly due to a greater orientation of the components in the blends than in the pure components.