화학공학소재연구정보센터
Applied Catalysis A: General, Vol.215, No.1-2, 191-197, 2001
Sulfated zirconia: attempt to use n-butylamine to measure acidity
Efforts to measure Bronsted acidity using the chemisorption of n-butyl amine and quantifying the number of Bronsted sites as being equal to the butenes and the ammonia formed during temperature-programmed heating was unsuccessful. Rather, it was observed that even at ambient temperature, chemisorption of n-butyl amine was accompanied by oxidation/reduction reactions that produced water, CO2 and oxides of sulfur. The results suggest that oxidation/reduction reactions initiate the conversion of hydrocarbons by this catalyst at low temperatures.