Journal of Chemical Physics, Vol.107, No.8, 2775-2781, 1997
Nuclear spin relaxation of spin one-half nuclei in the presence of neighboring higher-spin nuclei
The basis of scalar relaxation of the second kind and related features involving the secular approximation and separation of time scales are investigated in the motional regime where the extreme narrowing approximation fails. Using second order perturbation theory, it is demonstrated that significant differences exist between the derived results and conventional treatments. Extensions of the described approach are readily apparent. (C) 1997 American Institute of Physics.