Inorganic Chemistry, Vol.36, No.17, 3580-3581, 1997
Isolation of the stereoisomers of [{Ru(bpy)(2)}(2){Os(bpy)(2)}(mu-HAT)](6+) (HAT=1,4,5,8,9,12-hexaazatriphenylene; bpy=2,2'-bipyridine)
The stereoisomers of the trinuclear Ru2Os species [{Ru(bpy)(2)}(2){Os(bpy)(2)}(mu-HAT)](6+) (HAT = 1,4,5,8,9,12-hexaazatriphenylene; bpy =2,2'-bipyridine) have been isolated using a combination of stereoselective syntheses and chromatographic procedures and characterized by NMR and CD spectroscopy.