화학공학소재연구정보센터
Biomass & Bioenergy, Vol.7, No.1-6, 285-289, 1994
ENERGY AND CHEMICALS FROM RICE HUSK
Rice husk is the only agro residue having maximum siliceous ash content and available in dry form. The present work on rice husk describes processes for producing controlled carbon-silica mixtures in amorphous form, electronic-grade potassium silicate and activated carbon. Rice husk is first pyrolised in a reactor at less than 973 K to obtain the char which is subsequently heated and activated with steam at 1073-1173 K for about 1 h in another reactor. The char is leached with HCl. Analysis of the leached char indicates that it is amorphous in nature and contains mainly 40% carbon and 56% silica with small quantities of volatile matter. The utility of the material as filler for reinforcement of rubbers is tested. Test results show that a tenfold increase in tensile strength and modulus of elasticity can be achieved with 100 phr. In another development, the leached char is digested with 10-15% KOH solution in the temperature range of 303-373 K for about 1-10 h. It is found that electronic-grade potassium silicate could be easily produced compared to the conventional method of fusion of sand with alkali at 1273-1473 K. The residue from this process is a good-quality activated carbon. A process flowsheet is presented for producing these chemicals with energy recovery aspects from rice husk.