Biomass & Bioenergy, Vol.8, No.2, 117-120, 1995
OIL PRODUCTION FROM GARBAGE BY THERMOCHEMICAL LIQUEFACTION
Garbage was converted directly into oil by thermochemical liquefaction for the recovery of energy in the form of liquid fuel. The garbage with a moisture content of about 90 wt% was prepared by mixing cabbage, boiled rice, boiled and dried sardine, butter, and the shell of short-necked clam. The mixture was heated under pressurized nitrogen at 250 degrees, 300 degrees, or 340 degrees C for 0.1, 0.5, or 2 h, with or without sodium carbonate as a catalyst (0 or 4% on a dry solid basis). Oil yield and its properties strongly depended on catalyst addition and reaction temperature, while holding time showed no marked effect. Oil was obtained in the highest yield of 27.6% on an organic basis under the following conditions: catalyst addition, 4 wt%; temperature, 340 degrees C; pressure, 18 MPa; and holding time, 0.5 h. The oil had a calorific value of 36 MJ kg(-1) and a viscosity of 53,000 mPas at 50 degrees C. Its carbon content, hydrogen content, nitrogen content and oxygen content were 73.6, 9.1, 4.6 and 12.7%, respectively.
Keywords:THERMOCHEMICAL LIQUEFACTION;CATALYTIC LIQUEFACTION;OIL PRODUCTION;GARBAGE;MUNICIPAL SOLID WASTE;BIOMASS