Ash samples were collected from a dumping site (fly ash) and an electrostatic precipitator (ESP ash) of a 440 MW thermal power plant for characterization Analysis of ash samples showed that the major matrix elements in ni ash were Si and Al together with significant percentages of K, Fe, Ca and Mg. Some of the biologically-toxic elements, Ni, Cr, Pb, B and Mo, were also present in substantial amounts. Ash collected directly from electrostatic precipitator (ESP ash) was finer in texture, lower in pH and generally richer in nutrients than the ash collected from dumping sites (fly ash). The saturation moisture percentages of both the ashes were higher, but the bulk density was lower, than the normal cultivated soils. Calcium was the dominant cation of the exchange complex, followed by Mg2+ Na+ and K+. Contents of available sulphur were quite high. Among DTPA extractable micronutrients, only iron was present in significant amounts, but the contents of hazardous constituents were very low. Compositions of water-soluble constituents of both the ashes were substantially affected by water: fly ash ratio and decreased with dilution. The rare of release of sodium was found to be much less than calcium and magnesium.