Catalysis Today, Vol.46, No.2-3, 107-115, 1998
Catalytic partial oxidation of methane over Ni-, Co- and Fe-based catalysts
Partial oxidation of methane to synthesis gas has been investigated over Fe-, Co- and Ni-based catalysts in fixed bed reactor in view of a possible application in a fluidized bed reactor. Catalytic testing of the oxidic catalysts show an increasing activity for total oxidation of methane in the following order: Fe2O3>CoO>NiO. After reduction of the metal, the Ni and Co catalysts give equilibrium conversion to synthesis gas. Co is much more easier oxidized compared to Ni at decreasing temperature under experimental conditions and equilibrium is not followed at temperatures below 550 degrees C. Low reforming activity is obtained over the Fe catalyst. Investigations at 1000-1100 degrees C are necessary to further explore Fe as a reforming catalyst.