화학공학소재연구정보센터
Chemical Engineering & Technology, Vol.18, No.4, 278-283, 1995
DEACTIVATION KINETICS AND MODELING OF COKE REMOVAL UNDER SUPERCRITICAL CONDITIONS FOR THE EXAMPLE OF ETHYLBENZENE DISPROPORTIONATION
Deactivation kinetics and coke removal kinetics were derived from experimental studies on the disproportionation of ethylbenzene with a protonated Y-faujasite (Z-14) in a loop reactor under supercritical conditions. Derivation of the steady stare kinetics of ethylbenzene disproportionation permitted determination of the catalyst activity. At small educt mole fractions of ethylbenzene, owing to the modest removal of coke the deactivation kinetics can be described by a power relationship. The rate of coke removal can be correlated with the activity and the deactivation rate of the catalyst.