Fluid Phase Equilibria, Vol.180, No.1-2, 299-311, 2001
Solid-liquid equilibria based on an equation of state for chain fluids
Solid-liquid equilibria were studied using an equation of state previously developed for fluids containing chain-like molecules. The method was used to correlate solubilities of normal alkanes and aromatic compounds with high molecular mass in hydrocarbon solvents. With one temperature independent parameter for the interaction energy, good agreement can be obtained between calculated results and experimental data for selected systems.
Keywords:molecular thermodynamic model;solid-liquid equilibrium;solubility;normal alkane;aromatic hydrocarbon