Journal of Chemical Physics, Vol.116, No.10, 4221-4227, 2002
An improved model for ternary nucleation of sulfuric acid-ammonia-water
A revised homogeneous ternary nucleation model in H2O-H2SO4-NH3 vapors is presented. The model is based on a self-consistent version of classical nucleation theory with a rigorous treatment of nucleation kinetics. The calculation of equilibrium vapor pressures is completely revised and the effect of H2O-H2SO4 hydration is considered in detail. Compared to earlier models, the new model is able to predict nucleation rates over a wider range of temperatures and trace gas concentrations. A considerable dependence on relative humidity is found. The critical clusters corresponding to significant nucleation rates typically contain less than ten molecules and consist almost exclusively of H2SO4 and NH3.