화학공학소재연구정보센터
Journal of Chemical Physics, Vol.116, No.10, 4252-4265, 2002
Thermal effects in dynamics of interfaces
Dynamical Ginzburg-Landau theory is applied to the study of thermal effects of motion of interfaces that appear after different phase transitions. These effects stem from the existence of the surface thermodynamic properties and temperature gradients in the interfacial transition region. Thermal effects may be explained by the introduction of a new thermodynamic force exerted on the interface, called here Gibbs-Duhem force, and the internal energy density flux through the interface. The evolution equations for the interfacial motion are derived. For the experimental verification of the thermal effects during continuous ordering the expression is derived for the amplitude of temperature waves.