Journal of Chemical Physics, Vol.116, No.16, 6910-6913, 2002
Relative sizes of atoms observed in electron momentum densities
The radial electron momentum densities I(p) of atoms are known to reveal several local maxima and minima. For the 103 atoms from H to Lr in their ground states, we report that the reciprocal momenta 1/p(max) and 1/p(min), where p(max) and p(min) are the locations of the maxima and minima in I(p), respectively, have good linear correlations with the relative sizes R of atoms, defined based on the spherically averaged densities rho(r) in position space.