Journal of Industrial and Engineering Chemistry, Vol.8, No.3, 276-282, May, 2002
Modeling of Facilitated Transport in Solid Membranes Containing Various Fixed Site Carriers
E-mail:
The extended series resistor-capacitor (RC) circuit model was developed to account for the effects of various kinds of carriers incorporated in the solid membranes on a facilitated mass transport. The sensitivity analysis based on the arbitrarily chosen reference state shows the degree of sensitivity as follows: the extent of pressure fluctuation > the number of hypothetical layers > the ratio of the total carrier concentration to the solute solubility by Henry's law ≒ the time scale ratio of diffusion to chemical reaction > the combining driving force for facilitated transport. Furthermore, the model can describe multiple diffusional pathways from 4 to infinity depending on the number of different types of carriers, which can occurs in a real system.
- Nishide H, Kawakami H, Kurimura Y, Tsuchida E, J. Am. Chem. Soc., 111, 7175 (1989)
- Hsiue GH, Yang JM, Lee PS, Liaw CY, J. Membr. Sci., 28, 3363 (1990)
- Delaney MS, Reddy D, Wessling RA, J. Membr. Sci., 49, 15 (1990)
- Shim JS, Kim UY, Kang YS, Kim BG, Hong JM, J. Korean Ind. Eng. Chem., 1(2), 140 (1990)
- Hong JM, Kang YS, Korea Polym. J., 8(1), 1 (2000)
- Nishide H, Ohyanagi M, Okada O, Tsuchida E, Macromolecules, 20, 417 (1987)
- Cussler EL, Aris R, Bhown A, J. Membr. Sci., 43, 149 (1989)
- Noble RD, J. Membr. Sci., 50, 207 (1990)
- Kang YS, Hong JM, Jang J, Kim UY, J. Membr. Sci., 109(2), 149 (1996)
- Hong JM, Kang YS, Jang J, Kim UY, J. Membr. Sci., 109(2), 159 (1996)
- Hong SU, Won J, Park HC, Kang YS, J. Membr. Sci., 163(1), 103 (1999)
- Jin JH, Hong SU, Won J, Kang YS, Macromolecules, in press
- Barrer RM, J. Membr. Sci., 18, 25 (1984)