화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.19, No.3, 400-405, May, 2002
Observations on Combustion Front Propagation in Self-Propagating High-Temperature Synthesis Process Producing Refractory Ceramics
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High-temperature refractory ceramics can be produced in the combustion regime by using self-propagating, high-temperature synthesis (SHS) processes. The numerical simulation of the SHS process in a simplified diffusionreaction system is investigated. The SHS process is simplified by the one- and two-dimensional pseudo-homogeneous environment. The stiff equations of the SHS process are solved by using finite difference methods on twodimensional adaptive meshes. Travelling waves with constant patterns are observed for adiabatic and nonadiabatic systems. For higher values of heat of reaction and activation energy, the combustion front starts to oscillate. Single and complex oscillating waves are detected. In oscillating combustion fronts, the temperature can overshoot the adiabatic temperature to result in the complete conversion of solid reactants. In two dimensional systems, travelling, fingering, and rotating waves are detected in the combustion synthesis process.
  1. Agrafiotis CC, Puszynski JA, Hlavacek V, J. Mater. Sci., 22, 710 (1987) 
  2. Aldushin AP, Kasparyan SG, Fiz. Gor. Vzryva, 17, 37 (1981)
  3. Dankekar HW, Puszynski JA, Hlavacek V, AIChE J., 36, 1649 (1990) 
  4. Dankekar HW, Puszynski JA, Hlavacek V, "Dynamic Modeling and Simulation of Gas-Solid Reactions in Self-Propagating Regime," Ceramics Today-Tomorrow's Ceramics, Elsevier Science, 1207 (1991)
  5. Dimitriou P, Puszynski JA, Hlavacek V, Combust. Sci. Technol., 68, 101 (1989)
  6. Kim SH, Hlavacek V, Physica D, 10, 413 (1984) 
  7. Kim SH, Park HS, Korean J. Chem. Eng., 10(4), 226 (1993)
  8. Merzhanov AD, Borovinskaya IP, Combust. Sci. Technol., 10, 195 (1975)
  9. Munir ZA, Holt JB, J. Mater. Sci., 22, 710 (1987) 
  10. Park CH, M.S. Thesis, State University of New York at Buffalo (1983)
  11. Shkadinskii KG, Khaikin BI, Merzahanov AG, Combust. Explosives Shock Waves, 1, 19 (1971)
  12. Toth LE, "Transition Metal Carbides and Nitrides," Academic Press, New York (1971)